Three-dimensional imaging of colloidal glasses under steady shear.
نویسندگان
چکیده
Using fast confocal microscopy we image the three-dimensional dynamics of particles in a yielded hard-sphere colloidal glass under steady shear. The structural relaxation, observed in regions with uniform shear, is nearly isotropic but is distinctly different from that of quiescent metastable colloidal fluids. The inverse relaxation time tau(alpha)(-1) and diffusion constant D, as functions of the local shear rate gamma*, show marked shear thinning with tau(alpha)(-1) proportional to D proportional to gamma*(0.8) over more than two decades in gamma*. In contrast, the global rheology of the system displays Herschel-Bulkley behavior. We discuss the possible role of large scale shear localization and other mechanisms in generating this difference.
منابع مشابه
Shear-induced anisotropic decay of correlations in hard-sphere colloidal glasses
Spatial correlations of microscopic fluctuations are investigated via real-space experiments and computer simulations of colloidal glasses under steady shear. It is shown that while the distribution of one-particle fluctuations is always isotropic regardless of the relative importance of shear as compared to thermal fluctuations, their spatial correlations show a marked sensitivity to the compe...
متن کاملLocal shear transformations in deformed and quiescent hard-sphere colloidal glasses.
We perform a series of deformation experiments on a monodisperse, hard-sphere colloidal glass while simultaneously following the three-dimensional trajectories of roughly 50,000 individual particles with a confocal microscope. In each experiment, we deform the glass in pure shear at a constant strain rate [(1-5)×10(-5) s(-1)] to maximum macroscopic strains (5%-10%) and then reverse the deformat...
متن کاملStructural rearrangements that govern flow in colloidal glasses.
Structural rearrangements are an essential property of atomic and molecular glasses; they are critical in controlling resistance to flow and are central to the evolution of many properties of glasses, such as their heat capacity and dielectric constant. Despite their importance, these rearrangements cannot directly be visualized in atomic glasses. We used a colloidal glass to obtain direct thre...
متن کاملNonlinear Rheological Properties of Dense Colloidal Dispersions Close to a Glass Transition under Steady Shear
The nonlinear rheological properties of dense colloidal suspensions under steady shear are discussed within a first principles approach. It starts from the Smoluchowski equation of interacting Brownian particles in a given shear flow, derives generalized Green-Kubo relations, which contain the transients dynamics formally exactly, and closes the equations using mode coupling approximations. She...
متن کاملMode-coupling analysis of residual stresses in colloidal glasses.
We present results from computer simulation and mode-coupling theory of the glass transition for the nonequilibrium relaxation of stresses in a colloidal glass former after the cessation of shear flow. In the ideal glass, persistent residual stresses are found that depend on the flow history. The partial decay of stresses from the steady state to this residual stress is governed by the previous...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید
ثبت ناماگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید
ورودعنوان ژورنال:
- Physical review letters
دوره 99 2 شماره
صفحات -
تاریخ انتشار 2007